Not for shopping or lunch, but Montgomery Woods is a great place to visit when going to Orr. It's just down the road a bit from the hot springs and there are some nice peaceful trails to walk along.

Hopland has the Bluebird Cafe, and Mendocino Brewing Co. Both are excellent.

There's also the Solar Living Institute, which is cool.
www.solarliving.org/

Temple of Ten Thousand Buddhas! Take Talmadge exit off of 101 in Ukiah. Go east about two miles. You can't miss it. They have a terrific vegan restaurant too.

not exactly sure if its on the way, or not, it might have just been close enough to drive to orr from....i wasnt driving so i dont recall the route.

anyhoo,
i like the lil town of willits. 101 passes through it, you go under a big arch that says "willits - gateway to the redwoods" (love that arch)

its a cute lil town with a yummy burrito place, a nice pub with a patio, and a few cute shops. been going to willits in the summertime for years on the way to private events at 'Camp and Sons'. if you eat at the burrito place, theres a lil patio in the back where you can sit and eat . their burritos are yummers and so are the smoothies. and take a look around, if you should see a friendly black and white cat hangin out, say hello to "crook" - he's a sweetie!

just about a block away from the burrito place you'll see a tattoo shop "soul tattoo". stephen;s a great tattoo artist, if you can catch him there. he has odd hours. and right next door is a cute lil store with pretty hippie dresses and tops and belly dancer-ish clothing. i would buy the entire store if i could. hehe

also nearby is the eel river. which is nice to swim in too. swim with little fishies and also swing on the rope swing and cannonball into the water below.

yay mendocino!